Chemistry Letters

INFRARED AND RAMAN SPECTROSCOPIC STUDIES ON MOLECULAR CONFORMATIONS OF F (CH 2) n F (n= 3–6)

H Matsuura, M Sakakibara, H Murata

Index: Matsuura, Hiroatsu; Sakakibara, Masaaki; Murata, Hiromu Chemistry Letters, 1982 , p. 951 - 952

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Abstract

The infrared and Raman spectra of F (CH 2) n F (n= 3–6) were measured and analyzed on the basis of the normal coordinate treatment. The spectral analyses indicated that the molecule in the solid state takes the gauche-gauche conformation for n= 3, gauche-trans- gauche'for n= 4, gauche-trans-trans-gauche for n= 5, and gauche-trans-trans-trans- gauche'for n= 6.