Reactions of trifluoromethylthiocopper with halomethanes

S Munavalli, DI Rossman, DK Rohrbaugh…

Index: Munavalli; Rossman; Rohrbaugh; Ferguson; Durst Journal of Fluorine Chemistry, 1996 , vol. 76, # 1 p. 7 - 13

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Citation Number: 19

Abstract

The reaction of trifluoromethylthiocopper with halomethanes, namely di-and triiodo-, dibromodichloro-, dibromochlorofluoro-, dibromo-difluoro-, bromochlorofluoro-, phenyltrichloro-, bromocyano-and dibromofluoro-methanes, has been investigated in detail. In addition to the expected compounds, the formation of unusual products such as bis (trifluoromethyl) trithiocarbonate, dimethyl (trifluoromethylthio) benzene, bis ( ...