9??Azidoacridine and 9??acridinylnitrene

…, D Kvaskoff, PV Bernhardt, C Wentrup

Index: Taherpour, Avat Arman; Kvaskoff, David; Bernhardt, Paul V.; Wentrup, Curt Journal of Physical Organic Chemistry, 2010 , vol. 23, # 4 p. 382 - 389

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Citation Number: 12

Abstract

Abstract Matrix photolysis as well as flash vacuum thermolysis (FVT) of 9-azidoacridine affords 9-acridinylnitrene, which is characterized by its IR and ESR spectra and is photochemically inert. FVT above 600 C yields a mixture of the five isomeric cyanocarbazoles. Microwave-assisted reaction with diethyl-and dipropylamines in solution affords acridinylformamidine and acridinylpropionamidine, respectively. Microwave- ...