Canadian Journal of Chemistry

One-electron photooxidation of carbazole in the presence of carbon tetrachloride. Part II. Carbon tetrachloride as a reaction medium. Use of ammonia after irradiation …

B Zelent, G Durocher

Index: Zelent, Bogumil; Durocher, Gilles Canadian Journal of Chemistry, 1982 , vol. 60, p. 2442 - 2450

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Citation Number: 15

Abstract

In part I of this series of papers we proposed the mechanism of electron transfer as the primary photochemical reaction in the carbazole-carbon tetrachloride system along with a secondary photochemical reaction initiated by transformations of the radical cation of carbazole in the solvent cage resulting in intermediates: In this paper we discuss the influence of ammonia, used after and during irradiation, on the mechanism of secondary ...