Journal of the American Chemical Society

PSEUDO BASES IN THE ISOXAZOLE SERIES. THIRD PAPER

EP Kohler, CL Bickel

Index: Kohler, Bickel Journal of the American Chemical Society, 1930 , vol. 52, p. 4943,4948

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Abstract

The pseudo bases that have been described in earlier papers of this series are derived from isoxazoles in which all available positions are filled with hydrocarbon residues. In all these cases the rearrangement of the true base results in a pseudo base in which the hydroxyl group occupies the 5-position. In order to determine whether this mode of rearrangement is altered by an acidic group in this position, we have alkylated a ketonic isoxazole and ...