Phosphorus, Sulfur, and Silicon

Amine exchange reactions in ionic liquid

G Rashinkar, S Pore, R Salunkhe

Index: Rashinkar, Gajanan; Pore, Santoshkumar; Salunkhe, Rajeshree Phosphorus, Sulfur and Silicon and the Related Elements, 2009 , vol. 184, # 7 p. 1750 - 1758

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Citation Number: 6

Abstract

An operationally simple, inexpensive, efficient, and environmentally friendly protocol for the amine exchange reactions of 3-N, N-dimethylaminopropiophenone and N, N- dimethylaminomethylferrocene with primary aryl amines is developed using the ionic liquid [bmim] PF 6 as a solvent. The recovered ionic liquid can be reused for several cycles with constant activity.