Réaction entre solvant et espèces intermédiaires apparues lors de l'électroréduction-acylation de la fluorènone et de la fluorènone-anil dans l'acétonitrile

C Degrand, G Belot, PL Compagnon…

Index: Degrand, Chantal; Belot, Gerard; Compagnon, Paul-Louis; Gasquez, Francoise Canadian Journal of Chemistry, 1983 , vol. 61, p. 2581 - 2589

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Citation Number: 7

Abstract

The electrogenerated anions-CH2CN induce the conversion of the various reduction- acylation products of fluorènone 1 a and its anil 1 b in acetonitrile into 1 a and 1 b; this phenomenon is controlled by the fortuitous introduction of molecular oxygen. The-CH2CN anions catalyse the transformation of 1 a and 1 b into fluorenylideneacetonitrile (FlC= CHCN) 17, convertible into the nitriles FlC= CHC (CN)= C (NH2) CH3 8, FlC= C (CN) ...