Catalysis of the hydrolysis of esters of phosphorus acids byn-decylammonium chloride/n-decylamine mixed micelles

…, VE Bel'skii, SB Fedorov, BE Ivanov

Index: Bakeeva; Kudryavtseva; Bel'skii; Fedorov; Ivanov Russian Chemical Bulletin, 1996 , vol. 45, # 8 p. 1900 - 1903

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Abstract

Abstract The effect of n-decylammonium chloride/n-decylamine mixed micelles on the rate of hydrolysis of aryl esters of acids of four-coordinate phosphorus was studied spectrophotometrically. The shape of the concentration curves is characteristic of the micellar catalysis reactions. The binding constants of the substrate, critical micelle concentrations, and the rate constants in the micellar phase were determined. A specific ...