The Journal of Organic Chemistry

Fully Esterified Phosphates with Dissimilar Organic Groups Attached to the Phosphate Group1

I Dilaris, G Eliopoulos

Index: Dilaris,I.; Eliopoulos,G. Journal of Organic Chemistry, 1965 , vol. 30, p. 686 - 689

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Citation Number: 6

Abstract

All efforts to synthesize phosphate esters of the type RIR~ R~ PO~ have given intractable compounds. Only three such stable crystalline esters have been isolated, but we were unable to resolve them. An unexpected product, tri-p-bromobenzyl phosphate, is obtained from the reaction of silver n-amyl p-nitrobenzyl phosphate with p-bromobenzyl iodide.