Stille coupling involving bulky groups feasible with gold cocatalyst

…, D Carrasco, MH Pérez??Temprano…

Index: Delpozo, Juan; Carrasco, Desiree; Perez-Temprano, Monica H.; Garcia-Melchor, Max; Alvarez, Rosana; Casares, Juan A.; Espinet, Pablo Angewandte Chemie - International Edition, 2013 , vol. 52, # 8 p. 2189 - 2193 Angew. Chem., 2013 , vol. 125, # 8 p. 2245 - 2249

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Citation Number: 24

Abstract

There is a growing interest in bimetallic catalysis, a synthetic approach combining two or more non-main-group-metal catalysts working in tandem.[1] A main-group metal is often involved as the nucleophilic reagent. The aim of bimetallic catalysis is to take advantage of the specific behavior of each catalyst in new one-pot synthetic routes. For the Au/Pd couple it is known that the Au/Pd transmetalation, a step which is hoped to connect the palladium ...