Organometallics

Palladium-catalyzed regio-and stereoselective cross-coupling of Baylis-Hillman adducts and bimetals: a novel method for the synthesis of substituted allylsilanes and …

GW Kabalka, B Venkataiah, G Dong

Index: Yu, Su; Li, Nan-Sheng; Kabalka, George W. Journal of Organic Chemistry, 1999 , vol. 64, # 16 p. 5822 - 5825

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Citation Number: 24

Abstract

Cross-coupling reactions between Baylis-Hillman acetate adducts and bimetallic reagents (Si-Si, Ge-Ge) catalyzed by a phosphine-free palladium complex are described. 3- Substituted-2-carbonylallylsilanes and germanium reagents were isolated in high yields.