Carbohydrate research

Total synthesis of tunicamycin

T Suami, H Sasai, K Matsuno, N Suzuki

Index: Suami, Tetsuo; Sasai, Hiroaki; Matsuno, Kazuhiro; Suzuki, Nobuo Carbohydrate Research, 1985 , vol. 143, p. 85 - 96

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Citation Number: 32

Abstract

Abstract The first total synthesis of tunicamycin V, a major component of tunicamycin homologus, is described. Condensation of 2-acetamido-2-deoxy-4, 6-O-isopropylidene-3-O- propanoyl-α-d-glucopyranose with 1-[(11R)-2, 3, 5, 8, 9-penta-O-acetyl-10-( ...