The Journal of Organic Chemistry

Free-radical chain substitution reactions (SH2') of alkenyl-, alkynyl-, and (alkenyloxy) stannanes

GA Russell, LL Herold

Index: Russell, Glen A.; Herold, Lourdes Lucas Journal of Organic Chemistry, 1985 , vol. 50, # 7 p. 1037 - 1040

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Citation Number: 50

Abstract

Glen A. Russell* and Lourdes Lucas Herold Department of Chemistry, Iowa State University, Ames, Iowa 50011 Received September 20, 1984 ... Free-radical chain substitution reactions of allyltributylstannane were observed with PhSSPh, PhCH2SSCH2Ph, PhSeSePh, PhS02Cl, n-PrS02C1, or CC13S02C1, where the attacking radicals leading to allylic rearrangement with displacement of Bu3Sn. were PhS., PhCH2S., PhSe, PhS02., n-PrSO,., and CCl,., ...