Stereoselective Synthesis of Stannylated Dehydropiperidines and Dehydroazepanes

…, S Stecko, I Beaudet, JP Quintard…

Index: Quintard, Jean-Paul; Elissondo, Bernard; Mouko-Mpegna, David Journal of Organometallic Chemistry, 1983 , vol. 251, # 2 p. 175 - 188

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Abstract

Abstract An efficient allylation and butenylation of N-alkoxycarbonyl-2-tributylstannyl-1, 3- oxazolidines derived from (S)-vinylglycinol or (S)-styrylglycinol is described. After conversion of the stannylated azadienes into stannylated dienyl oxazolidinones, a ring-closing