Journal of Organic Chemistry

Reaction of tris (hydroxymethyl) phosphine with substituted ureas

AB Pepperman, DJ Daigle, SL Vail

Index: Pepperman,A.B. et al. Journal of Organic Chemistry, 1976 , vol. 41, # 4 p. 675 - 678

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Citation Number: 9

Abstract

The reaction of tris (hydroxymethy1) phosphine with monosubstituted and unsymmetrically disubstituted ureas has been shown to produce tris (4-substituted ureidomethy1) phosphine oxides. The products were characterized by ir spectra, NMR spectra, and elemental analyses. The NMR spectrum for tris (4-phenylureidomethy1) phos-phine oxide showed a triplet for the NH attached to the phosphorus methylene, appearing at a higher field than ...