Absolute rate expressions for intramolecular displacement reactions of primary alkyl radicals at sulfur

JA Franz, DH Roberts, KF Ferris

Index: Franz, James A.; Roberts, David H.; Ferris, Kim F. Journal of Organic Chemistry, 1987 , vol. 52, # 11 p. 2256 - 2262

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Citation Number: 43

Abstract

Arrhenius parameters are presented for the intramolecular displacement reactions of 4- (alky1thio) butyl radicals, where alkyl= benzyl, propyl, and tert-butyl, giving tetrahydrothiophene and the corresponding alkyl radical (E). Arrhenius expressions were ...

~21%

~72%

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