Tetrahedron Letters

On the mechanism of carbon-hydrogen activation in gif-type reactions. Kinetic isotopic effects in pyridine solution.

D Darío

Index: Barton, Derek H. R.; Doller, Dario; Geletii, Yurii V. Tetrahedron Letters, 1991 , vol. 32, # 31 p. 3811 - 3814

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Abstract

Abstract Kinetic isotopic effects (KIE) were measured for oxidation, bromination and selenylation of cC 6 H 12/cC 6 D 12 in pyridine solution for different Gif-type, Fenton and other systems. The comparison of KIE and relative reactivity data for the pair cC 5 H 10/cC 6