Tetrahedron letters

Heck reaction with heteroaryl halides in the presence of a palladium-tetraphosphine catalyst

F Berthiol, M Feuerstein, H Doucet, M Santelli

Index: Berthiol, Florian; Feuerstein, Marie; Doucet, Henri; Santelli, Maurice Tetrahedron Letters, 2002 , vol. 43, # 32 p. 5625 - 5628

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Citation Number: 62

Abstract

cis, cis, cis-1, 2, 3, 4-Tetrakis (diphenylphosphinomethyl) cyclopentane/1 2 [PdCl (C3H5)] 2 system catalyses efficiently the Heck reaction of heteroaryl halides with n-butyl acrylate, styrene, vinylpyridine and vinyl ether derivatives. High turnover numbers can be obtained for the reactions with halo pyridines, quinolines, furans or thiophenes.