Location of hydroperoxide groups in monohydroperoxides formed by chlorophyll-photosensitised oxidation of unsaturated esters

D Cobern, JS Hobbs, RA Lucas…

Index: Cobern,D. et al. Journal of the Chemical Society [Section] C: Organic, 1966 , p. 1897 - 1902

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Citation Number: 29

Abstract

Monohydroperoxides were isolated from chlorophyll-photosensitised oxidation of methyl oleate, methyl linoleate, methyl linolenate, and ethyl arachidonate. The positions of the hydroperoxide substituent were determined by two methods of analysis of the saturated hydroxy-esters formed by catalytic hydrogenation. Gas–