Journal of the American Chemical Society

THE REACTIVITY OF ATOMS AND GROUPS IN ORGANIC COMPOUNDS. V. THIRD CONTRIBUTION ON THE CARBON-CHLORINE BOND: THE RATES OF THE …

JF Norris, JT Blake

Index: Norris; Blake Journal of the American Chemical Society, 1928 , vol. 50, p. 1811

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Citation Number: 15

Abstract

1808 JAMES F. NORRIS AND JOHN TWISS BLAKE ... The method of Schulze* for the determination of side chain chlorine was used. In certain cases the time of refluxing the halide with the alcoholic soIution of silver nitrate was increased to two hours. Experiments with p- and o-chlorodiphenylcarbinol showed that the halogen in the ring was not removed by the solution of silver nitrate. The ethyl alcohol used in the determination of velocity constants was purified in the usual way and ...