Journal of the American Chemical Society

Allylation of aromatic compounds with organopalladium salts

RF Heck

Index: Heck,R.F. Journal of the American Chemical Society, 1968 , vol. 90, # 20 p. 5531 - 5534

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Citation Number: 167

Abstract

Abstract: Arylpalladium salts, prepared in situ from arylmercuric salts and palladium (I1) compounds, react with allylic halides at room temperature to produce allylaromatic derivatives. Moderate yields were obtained with a wide variety of aromatic compounds; even nitro, ester, and aldehyde groups could be present in the arylmercury compounds. llyl derivatives of aromatic compounds are readily A obtained by the reaction of aromatic ...

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