Synthesis and Spectroscopic Characterization of the First Symmetrically and Nonsymmetrically Substituted Fluorinated Emerald??Green Trannulenes C60F15R3 …

PA Troshin, EA Khakina, AV Zhilenkov…

Index: Troshin, Pavel A.; Khakina, Ekaterina A.; Zhilenkov, Alexander V.; Peregudov, Alexander S.; Troshina, Olesya A.; Kozlovskii, Viacheslav I.; Polyakova, Natalya V.; Lyubovskaya, Rimma N. European Journal of Organic Chemistry, 2010 , # 6 p. 1037 - 1045

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Citation Number: 5

Abstract

Abstract The first water-soluble C 3v-symmetrical trannulene derivatives of fluorofullerene C 60 F 18 possessing six carboxylic or ammonium ion groups have been synthesized and spectrally characterized. The stability of emerald-green aqueous solutions of these compounds was investigated. A novel synthetic route was developed for a step-by-step derivatization of C 60 F 18 with different organic C–H acids that yielded nonsymmetrically ...