Synthesis and chemical properties of 1, 3-dichloro-1, 3-dihydridodisilazanes

…, M Birot, J Dunoguès, G Bourgeois, M Pétraud

Index: Bacque, Eric; Pillot, Jean-Paul; Birot, M.; Dunogues, J.; Bourgeois, G.; Petraud, M. Journal of Organometallic Chemistry, 1994 , vol. 481, # 2 p. 167 - 172

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Citation Number: 16

Abstract

Abstract A trans-silylation route to 1, 3-dichloro-l, 3-dihydridodisilazanes, a novel class of polyfunctional disilazane, is described. Thus, heating hexamethyl-or heptamethyl-disilazane under reflux in the presence of an excess of dichlorohydrogenosilane R 1 SiHCl 2, led to compounds of formula (R 1 ClHSi) 2 NR 2 (R 1= Me, Et, Vi or Ph and R 2= H; R 1= Me and R 2= Me) in high yield. The exchange of chlorinated organosilicon moieties was strongly ...