Heteroatom Chemistry

One??pot synthesis of primary 1??aminophosphonates: Coupling reaction of carbonyl compounds, hexamethyldisilazane, and diethyl phosphite catalyzed by Al (OTf) 3

S Sobhani, Z Tashrifi

Index: Sobhani, Sara; Tashrifi, Zahra Heteroatom Chemistry, 2009 , vol. 20, # 2 p. 109 - 115

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Citation Number: 35

Abstract

Abstract Al (OTf) 3 has been utilized as a new and efficient catalyst for the selective synthesis of primary 1-aminophosphonates by a one-pot coupling reaction of various types of aldehydes/ketones, hexamethyldisilazane, and diethyl phosphite under solvent-free conditions.© 2009 Wiley Periodicals, Inc. Heteroatom Chem 20: 109–115, 2009; Published online in Wiley InterScience (www. interscience. wiley. com). DOI 10.1002/hc. 20517