Synthesis and Characterization of Diorganotin Compounds Containing Silicon and Germanium and Crystal Structure of Precursor Carboxy-Ethyltrichlorogermanium

MA Choudhary, M Mazhar, U Salma, S Ali…

Index: Aziz Choudhary; Mazhar; Salma; Ali; Qinglan; Molloy Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 2001 , vol. 31, # 2 p. 277 - 295

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Citation Number: 16

Abstract

Eight compounds of general formula [R1 (CH3) 2SiCH2] 2Sn-[O2CCH2 (R2) CHGeR3 3] 2 [R1= CH3, C2H5; R2= C6H5, C6H4OMe-3/4, R3= CH3, N (CH2CH2O) 3] have been synthesised from [R1 (CH3) 2SiCH2] 2SnCl2 and R3 3GeCH (R2) CH2CO2H in the presence of triethylamine.(Me3CCH2) 3SnO2CCH2 (R1) CHGe (R2) 3 [R1= C6H5, C6H4OMe-3; R2= N (CH2CH2O) 3] have been synthesised similarly from (Me3CCH2) ...