Total synthesis and biological evaluation of (+)-and (−)-bisanthraquinone antibiotic BE-43472B and related compounds

KC Nicolaou, J Becker, YH Lim, A Lemire…

Index: Mal, Dipakranjan; Ray, Sutapa; Sharma, Indrajeet Journal of Organic Chemistry, 2007 , vol. 72, # 13 p. 4981 - 4984

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Citation Number: 29

Abstract

... Journal of the American Chemical ... J. Am. Chem. Soc. ... figure Figure 3. X-ray-derived ORTEP drawing of compound 11. Having achieved the requisite carbon−carbon bond formation, we then turned our attention to the oxidation/aromatization of the so-obtained product 11. ...

~63%

~66%

~57%

~53%

~22%

~44%

~66%

First TDAE approach in quinonic series: Synthesis of new 2-s...

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Experiments directed towards the synthesis of anthracyclinon...

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