The preparation and some reactions of unsymmetrical acyl thioacyl sulfides

…, K Sugino, Y Matsuzawa, T Katada…

Index: Kato, Shinzi; Sugino, Katsumi; Matsuzawa, Yukihiko; Katada, Tomonori; Noda, Ippei; et al. Liebigs Annalen der Chemie, 1981 , # 10 p. 1798 - 1811

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Abstract

Abstract A number of unsymmetrical acyl thioacyl sulfides [RC (S) S (O) CR'] have been prepared and characterized by the reaction of piperidinium or sodium dithiocarboxylates with acyl chlorides or by desulfurization reaction of acyl thioacyl disulfides with triphenylphosphine. They are deep blue oils or light green crystals and very unstable thermally and for moisture. The n [RIGHTWARDS ARROW] π transitions of the ...

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