New trigonal tris (phosphine oxides)

…, KA Lyssenko, MY Antipin, EE Nifant'ev

Index: Pisareva; Petrovskii; Lyssenko; Antipin; Nifant'ev Russian Chemical Bulletin, 2004 , vol. 53, # 9 p. 2008 - 2012

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Citation Number: 2

Abstract

Abstract The reaction of 1, 1, 1-tris (chloromethyl) propane with diphenylphosphine under phase-transfer conditions afforded 1, 1, 1-tris (diphenylphosphinomethyl) propane, whose oxidation gave a previously unknown representative of trigonal tris (phosphine oxides), viz., stable 1, 1, 1-tris (diphenylphosphorylmethyl) propane. Its analogs, viz., bis (diphenylphosphoryl) diphenylphosphinomethane and tris (diphenylphosphoryl) methane, ...