A Selective Ru??Catalyzed Semireduction of Alkynes to Z Olefins under Transfer??Hydrogenation Conditions

C Belger, NM Neisius, B Plietker

Index: Belger, Christian; Neisius, N. Matthias; Plietker, Bernd Chemistry - A European Journal, 2010 , vol. 16, # 40 p. 12214 - 12220

Full Text: HTML

Citation Number: 43

Abstract

Our site uses cookies to improve your experience. You can find out more about our use of cookies in About Cookies, including instructions on how to turn off cookies if you wish to do so. By continuing to browse this site you agree to us using cookies as described in About Cookies. ... By using a readily available, air- and moisture-stable dihydrido–Ru complex, a variety of Z olefins are accessible under transfer-hydrogenation conditions with formic acid as the hydrogen ...

 Related Synthetic Route
Methyl 3-phenyl-2-propynoate Structure

4891-38-7

Methyl 3-phenyl...

~%

Methyl (2Z)-3-phenylacrylate Structure

19713-73-6

Methyl (2Z)-3-p...

Methyl 3-phenylpropanoate Structure

103-25-3

Methyl 3-phenyl...

Methyl 3-phenyl-2-propynoate Structure

4891-38-7

Methyl 3-phenyl...

~73%

Methyl (2Z)-3-phenylacrylate Structure

19713-73-6

Methyl (2Z)-3-p...

Methyl cinnamate Structure

103-26-4

Methyl cinnamate

4-Decyne Structure

2384-86-3

4-Decyne

~0%

cis-4-decene Structure

19398-88-0

cis-4-decene

trans-4-decene Structure

19398-89-1

trans-4-decene

4-Decyne Structure

2384-86-3

4-Decyne

~96%

cis-4-decene Structure

19398-88-0

cis-4-decene

trans-4-decene Structure

19398-89-1

trans-4-decene

4-Decyne Structure

2384-86-3

4-Decyne

~%

cis-4-decene Structure

19398-88-0

cis-4-decene

phenylpropyne Structure

673-32-5

phenylpropyne

~94%

Benzene,(1E)-1-propen-1-yl- Structure

873-66-5

Benzene,(1E)-1-...

phenylpropene Structure

766-90-5

phenylpropene

5-DECYN-1-OL Structure

68274-97-5

5-DECYN-1-OL

~0%

Z-5-Decen-1-ol Structure

51652-47-2

Z-5-Decen-1-ol

trans-5-Decen-1-ol Structure

56578-18-8

trans-5-Decen-1-ol

5-Decyne Structure

1942-46-7

5-Decyne

~97%

dec-5-ene Structure

7433-78-5

dec-5-ene

5-Decene, (5E)- Structure

7433-56-9

5-Decene, (5E)-

1-Pentyn-1-ylbenzene Structure

4250-81-1

1-Pentyn-1-ylbenzene

~0%

(Z)-1-(4-methylphenyl)-1-pentene Structure

7642-18-4

(Z)-1-(4-methyl...

TRANS-1-PHENYL-1-PENTENE Structure

16002-93-0

TRANS-1-PHENYL-...

phenylpropyne Structure

673-32-5

phenylpropyne

~0%

Benzene,(1E)-1-propen-1-yl- Structure

873-66-5

Benzene,(1E)-1-...

phenylpropene Structure

766-90-5

phenylpropene

2-Decyne Structure

2384-70-5

2-Decyne

~94%

cis-2-decene Structure

20348-51-0

cis-2-decene

2-Decene, (E)- Structure

20063-97-2

2-Decene, (E)-

Diphenylacetylene Structure

501-65-5

Diphenylacetylene

~0%

trans-Stilbene-d2 Structure

5284-44-6

trans-Stilbene-d2

cis-1,2-dideuterio-cis-stilbene Structure

3947-91-9

cis-1,2-dideute...

5-Decyne Structure

1942-46-7

5-Decyne

~0%

dec-5-ene Structure

7433-78-5

dec-5-ene

5-Decene, (5E)- Structure

7433-56-9

5-Decene, (5E)-

3-Decyne Structure

2384-85-2

3-Decyne

~94%

TRANS-3-DECENE Structure

19150-21-1

TRANS-3-DECENE

cis-3-decene Structure

19398-86-8

cis-3-decene

3-Decyne Structure

2384-85-2

3-Decyne

~0%

TRANS-3-DECENE Structure

19150-21-1

TRANS-3-DECENE

cis-3-decene Structure

19398-86-8

cis-3-decene


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