Oxygen Atom Transfer to a Half-Sandwich Iridium Complex: Clean Oxidation Yielding a Molecular Product

…, PS White, M Brookhart, JL Templeton

Index: Turlington, Christopher R.; White, Peter S.; Brookhart, Maurice; Templeton, Joseph L. Journal of the American Chemical Society, 2014 , vol. 136, # 10 p. 3981 - 3994

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Citation Number: 21

Abstract

The oxidation of [Ir (Cp*)(phpy)(NCArF)][B (ArF) 4](1; Cp*= η5-pentamethylcyclopentadienyl, phpy= 2-phenylene-κ C 1′-pyridine-κ N, NCArF= 3, 5-bis (trifluoromethyl) benzonitrile, B (ArF) 4= tetrakis [3, 5-bis (trifluoromethyl) phenyl] borate) with the oxygen atom transfer (OAT) reagent 2-tert-butylsulfonyliodosobenzene (sPhIO) yielded a single, molecular product at− 40° C. New Ir (Cp*) complexes with bidentate ligands derived by oxidation of ...

~60%

~44%

PdCl2 and N??Hydroxyphthalimide Co??catalyzed C sp 2 H Hydr...

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Nickel/zinc-mediated alkyl carbon-oxygen bond cleavage of al...

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