PdCl2 and N??Hydroxyphthalimide Co??catalyzed C sp 2 H Hydroxylation by Dioxygen Activation

Y Yan, P Feng, QZ Zheng, YF Liang…

Index: Yan, Yuepeng; Feng, Peng; Zheng, Qing-Zhong; Liang, Yu-Feng; Lu, Jing-Fen; Cui, Yuxin; Jiao, Ning Angewandte Chemie - International Edition, 2013 , vol. 52, # 22 p. 5827 - 5831 Angew. Chem., 2013 , vol. 125, # 22 p. 5939 - 5943,5

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Citation Number: 74

Abstract

Direct functionalization of CÀH bonds has been developed as a powerful strategy to form new chemical bonds.[1] Among them, transition-metal-catalyzed hydroxylation of CÀH bonds has received considerable attention because of the industrially important alcohol or phenol products.[2, 3] Despite the significant development in the past decades,[1, 2] catalytic hydroxylation of Csp2ÀH bonds still remains a very challenging task.