1, 4, 5, 8??Tetra??Azaphenanthrene Complexes of Copper (I) and Silver (I)

J Nasielski, R Nasielski??Hinkens…

Index: Nasielski, J.; Nasielski-Hinkens, R.; Heilporn, S.; Rypens, C.; Declercq, J. P. Bulletin des Societes Chimiques Belges, 1988 , vol. 97, # 11-12 p. 983 - 992

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Citation Number: 11

Abstract

Abstract Cu (l) and Ag (l) complexes of 1, 4, 5, 8-tetra-azaphenanthrene (TAP) and of two of its methylated derivatives (3, 6-dimethyl-and 2, 3, 6, 7-tetramethyl-) have been made and characterized. Their HNMR spectra are discussed. The structure of the complex Ag (TAP) 2 (NO 3), as determined by X-Ray crystallography, is that of a strongly folded and twisted square planar arrangement of the chelating ligands around the silver atom; the four Ag-N ...