Unsaturated Amines. XI. The Course of Formic Acid Reduction of Enamines1

NJ Leonard, RR Sauers

Index: Leonard, N. J.; Sauers, R. R. Journal of the American Chemical Society, 1957 , vol. 79, p. 6210 - 6214 Full Text View citing articles Show Details Muenzberg, F. K. Zeitschrift fuer Physikalische Chemie, Abteilung B: Chemie der Elementarprozesse, Aufbau der Materie, 1935 , vol. 31, p. 18 - 22 Full Text Show Details Gmelin Handbook: C: MVol.C4, 5.1.4, page 50 - 51

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Citation Number: 52

Abstract

The hydride of the formate ion becomes at-The relative rates of mercuric acetate oxidation of quinolizidine of deuterium-labeled formic acid (DCOOH, HCOOD, DCOOD). becomes attached to the@-carbon of the enamine grouping and that this step in the reduction process is reversible. ternary iminium formate receives favorable consideration as the intermediate. tached to the a-carbon of the original enamine grouping. and of quinolizidine-10-d ...