SYNTHESIS OF A NEW BICYCLIC NITROGEN RING. ISOGRANATANINE DERIVATIVES. PREPARATION OF AN ISOMER OF HOMOCOCAINE

SM McElvain, R Adams

Index: McElvain; Adams Journal of the American Chemical Society, 1923 , vol. 45, p. 2740,2747

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Citation Number: 15

Abstract

V VI VI1 With this substance available it is obvious that, by employing well-known reactions, isogranatanine and numerous other derivatives can be produced. The general properties of ethyl isogranatonine-carboxylate are of interest. The free base is a colorless liquid, the hydrochloride a white solid. Both Ruzicka'and Willstatter8 have studied amino P-ketonic esters of an analogous type and the latter has mentioned that they were thick oils which ...