Journal of fluorine chemistry

Vergleich der trifluormethylierungseigenschaften von (CF 3) Hg, CF 3 I und (CF 3) 2 te am beispiel der reaktionen mit cyclohexen, benzol und pyridin

D Naumann, B Wilkes, J Kischkewitz

Index: Naumann,D.; Wilkes,B. Journal of Fluorine Chemistry, 1985 , vol. 30, p. 73

Full Text: HTML

Citation Number: 43

Abstract

Abstract The trifluoromethylation reactions of (CF 3) 2 Hg, CF 3 I and (CF 3) 2 Te with cyclohexene, benzene and pyridine are compared under similar conditions. Photochemical as well as thermal reactions result in an increase of the reactivity in the series (CF 3) 2 Hg< CF 3 I⪡(CF 3) 2Te. The yields and the kind of products vary depending on the time of irradiation and the temperature. In all cases the best yields are obtained from the thermal ...