Nitration of cinnamic acids using cerium (IV) ammonium nitrate immobilized on silica

A Messere, A Gentili, I Garella, F Temussi…

Index: Messere, Anna; Gentili, Alessandra; Garella, Isidoro; Temussi, Fabio; Di Blasio, Benedetto; Fiorentino, Antonio Synthetic Communications, 2004 , vol. 34, # 18 p. 3317 - 3324

Full Text: HTML

Citation Number: 11

Abstract

Abstract Treatment of cinnamic acids with cerium (IV) ammonium nitrate supported on silica (CAN/SiO2) was used to synthesize nitro derivative and ipso substitution products. The position of the substituents defines the type and the yields of the products. This is the first example of an ipso substitution reaction by solid??phase approach.