Diethoxytriphenylphosphorane: a mild, regioselective cyclodehydrating reagent for conversion of diols to cyclic ethers: stereochemistry, synthetic utility, and scope

PL Robinson, CN Barry, JW Kelly…

Index: Journal of the American Chemical Society, , vol. 107, # 18 p. 5210 - 5219

Full Text: HTML

Citation Number: 57

Abstract

... Contribution from The William Rand Kenan, Jr., Laboratories of Chemistry, The University of North Carolina, Chapel Hill, North Carolina 2751 4. Received September 1, 1983 ... 1981, No. 171, 165. 0 1985 American Chemical Society Page 2. ... SOC.. Vol. 107, No. 18, 1985 521 1 ...

 Related Synthetic Route
(−)-Ethyl L-lactate Structure

687-47-8

(−)-Ethyl L-lactate

~%

(R)-(+)-Propylene oxide Structure

15448-47-2

(R)-(+)-Propyle...

(S)-(−)-Propylene oxide Structure

16088-62-3

(S)-(−)-Propyle...

Diethyloxytriphenylphosphorane Structure

86852-11-1

Diethyloxytriph...

1,3-Propanediol Structure

504-63-2

1,3-Propanediol

~%

Oxetane Structure

503-30-0

Oxetane

3-Ethoxy-1-propanol Structure

111-35-3

3-Ethoxy-1-propanol

2-BUTENE-1,4-DIOL Structure

821-11-4

2-BUTENE-1,4-DIOL

~%

2-Vinyloxirane Structure

930-22-3

2-Vinyloxirane

2,2-Dihydro-4,4,5,5-tetramethyl-2,2,2-triphenyl-1,3,2-dioxaphospholane Structure

49595-63-3

2,2-Dihydro-4,4...

~%

Pinacolone Structure

75-97-8

Pinacolone

Pinacol Structure

76-09-5

Pinacol

~%

Oxirane,2,2,3,3-tetramethyl- Structure

5076-20-0

Oxirane,2,2,3,3...

Pinacolone Structure

75-97-8

Pinacolone

2,3-Dimethylbut-3-en-2-ol Structure

10473-13-9

2,3-Dimethylbut...

Benzoin Structure

119-53-9

Benzoin

~%

stilbene oxide Structure

1439-07-2

stilbene oxide

(−)-Ethyl L-lactate Structure

687-47-8

(−)-Ethyl L-lactate

~%

(R)-(+)-Propylene oxide Structure

15448-47-2

(R)-(+)-Propyle...

(S)-(−)-Propylene oxide Structure

16088-62-3

(S)-(−)-Propyle...

(S)-(+)-Mandelic acid Structure

17199-29-0

(S)-(+)-Mandeli...

~%

(S)-Styrene oxide Structure

20780-54-5

(S)-Styrene oxide

1,2-bis(tosyloxy)-1-phenylethane Structure

1886-71-1

1,2-bis(tosylox...

~%

(S)-Styrene oxide Structure

20780-54-5

(S)-Styrene oxide

2-methyl-2-pentene Structure

625-27-4

2-methyl-2-pentene

~%

2-Methyl-3-pentanone Structure

565-69-5

2-Methyl-3-pentanone

1,3,2-dioxaphospholane Structure

96455-85-5

1,3,2-dioxaphos...

~25%

2-methyl-2,3-pentanediol Structure

7795-80-4

2-methyl-2,3-pe...

2-Methyl-3-pentanone Structure

565-69-5

2-Methyl-3-pentanone

N/A Structure

96481-55-9

N/A

1,3,2-dioxaphospholane Structure

96455-85-5

1,3,2-dioxaphos...

~%

2-Methyl-3-pentanone Structure

565-69-5

2-Methyl-3-pentanone

(S)-(+)-Mandelic acid Structure

17199-29-0

(S)-(+)-Mandeli...

~%

Styrene oxide Structure

96-09-3

Styrene oxide

1,3,2-dioxaphospholane Structure

96553-70-7

1,3,2-dioxaphos...

~%

Cyclohexanone Structure

108-94-1

Cyclohexanone


Home | MSDS/SDS Database Search | Journals | Product Classification | Biologically Active Compounds | Selling Leads | About Us | Disclaimer

Copyright © 2024 ChemSrc All Rights Reserved