Amino alcohol coordination in ruthenium (II)-catalysed asymmetric transfer hydrogenation of ketones

…, P Van Leeuwen, K Goubitz, AM Van Loon…

Index: Petra, Danielle G. I.; Kamer, Paul C. J.; Van Leeuwen, Piet W. N. M.; Goubitz, Kees; Van Loon, Arjen M.; De Vries, Johannes G.; Schoemaker, Hans E. European Journal of Inorganic Chemistry, 1999 , # 12 p. 2335 - 2341

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Citation Number: 48

Abstract

Keywords: Asymmetric catalysis / Transfer hydrogenation / Ruthenium / Amino alcohol ligands / X-ray structure ... The nature of ruthenium-amino alcohol precursors in the ... Based on the results of this study a series of new amino alcohol ligands was synthesised from easily available starting ... 2) that were synthesised from (nor)ephedrine. The structure of the catalyst precursor was examined through catalysis and ... NMR experiments. It was shown that the active ...