The Journal of Organic Chemistry

Adducts of anthrahydroquinone and anthranol with lignin model quinone methides. 1. Synthesis and characterization

LL Landucci, J Ralph

Index: Landucci, Lawrence L.; Ralph, John Journal of Organic Chemistry, 1982 , vol. 47, # 18 p. 3486 - 3495

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Citation Number: 40

Abstract

30 possible key intermediate was isolated. 6 The intermediate was characterized as the adduct 3a formed via the quinone methide 2a7-9 and anthrahydroquinone (AHQ), the twoelectron reduction product of AQ. 1 The structure of 3a was subsequently confirmed.'l* Also, the preparation of analogous AHQ and anthranol adducts with quinone methides derived from simple benzyl alcohols has recently been reported. llb