Tetrahedron: Asymmetry

Use of triazole-ring formation to attach a Ru/TsDPEN complex for asymmetric transfer hydrogenation to a soluble polymer

CM Zammit, M Wills

Index: Zammit, Charlotte M.; Wills, Martin Tetrahedron Asymmetry, 2013 , vol. 24, # 13-14 p. 844 - 852

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Citation Number: 10

Abstract

Abstract The cycloaddition of a chiral ligand containing a terminal alkyne to a soluble polymer containing an azide provides a convenient means for the attachment of an asymmetric transfer hydrogenation catalyst to a soluble polymer support. Using these ligands in complexes with Ru (II), gave good results in terms of conversion and enantioselectivity (up to 95% ee) in ketone reduction reactions.

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