Journal of the American Chemical Society

Catalytic asymmetric synthesis of optically active 2-alkanols via hydrosilylation of 1-alkenes with a chiral monophosphine-palladium catalyst

Y Uozumi, T Hayashi

Index: Journal of the American Chemical Society, , vol. 113, # 26 p. 9887 - 9888

Full Text: HTML

Citation Number: 281

Abstract

... We are particularly grateful to Professor SL Bender (University of California, Irvine) for sharing unpublished experimental methods with us. ... (c) Lukevics, E.; Belyakova, Z. V.; Pomerantseva, M. G.; Voronkov, MG In Journal of Organometallic ... 0 1991 American Chemical Society ...

 Related Synthetic Route
Ethanol Structure

64-17-5

Ethanol

octene Structure

111-66-0

octene

~%

1-Octanol Structure

111-87-5

1-Octanol

(R)-(−)-2-Octanol Structure

5978-70-1

(R)-(−)-2-Octanol

Ethanol Structure

64-17-5

Ethanol

octene Structure

111-66-0

octene

~%

1-Octanol Structure

111-87-5

1-Octanol

(R)-(−)-2-Octanol Structure

5978-70-1

(R)-(−)-2-Octanol

dodecene Structure

112-41-4

dodecene

Ethanol Structure

64-17-5

Ethanol

~%

1-Dodecanol Structure

112-53-8

1-Dodecanol

(R)-(-)-2-dodecanol Structure

99210-87-4

(R)-(-)-2-dodecanol

1-hexene Structure

592-41-6

1-hexene

Ethanol Structure

64-17-5

Ethanol

~%

Triethoxy(hexyl)silane Structure

18166-37-5

Triethoxy(hexyl...

N/A Structure

18166-36-4

N/A

4-Phenyl-1-butene Structure

768-56-9

4-Phenyl-1-butene

~%

Trichloro(4-phenylbutyl)silane Structure

17886-88-3

Trichloro(4-phe...

(S)-trichloro(4-phenylbutan-2-yl)silane Structure

83972-42-3

(S)-trichloro(4...

(S)-trichloro(4-phenylbutan-2-yl)silane Structure

83972-42-3

(S)-trichloro(4...

(R)-2-diphenylphosphinyl-2'-trifluoromethanesulfonyloxy-1,1'-binaphthalene Structure

132532-04-8

(R)-2-diphenylp...

~%

(S)-(-)-1-PHENYLETHANOL Structure

137769-29-0

(S)-(-)-1-PHENY...

1-hexene Structure

592-41-6

1-hexene

~%

n-Hexyltrichlorosilane Structure

928-65-4

n-Hexyltrichlor...

(R)-2-(trichlorosilyl)hexane Structure

137769-23-4

(R)-2-(trichlor...

N/A Structure

18151-52-5

N/A

1-hexene Structure

592-41-6

1-hexene

~%

n-Hexyltrichlorosilane Structure

928-65-4

n-Hexyltrichlor...

(R)-2-(trichlorosilyl)hexane Structure

137769-23-4

(R)-2-(trichlor...

1-hexene Structure

592-41-6

1-hexene

Ethanol Structure

64-17-5

Ethanol

~%

(R)-(-)-2-hexanol Structure

26549-24-6

(R)-(-)-2-hexanol

1-Hexanol Structure

111-27-3

1-Hexanol

(R)-2'-(Diphenylphosphinyl)-[1,1'-binaphthalen]-2-ol Structure

132548-91-5

(R)-2'-(Dipheny...

~%

(R)-2-Diphenyphosphino-2'-ethyl-1,1'-binaphthyl Structure

137769-32-5

(R)-2-Diphenyph...

Ethanol Structure

64-17-5

Ethanol

4-Phenyl-1-butene Structure

768-56-9

4-Phenyl-1-butene

~%

4-Phenylbutan-1-ol Structure

3360-41-6

4-Phenylbutan-1-ol

4-Phenyl-2-butanol Structure

2344-70-9

4-Phenyl-2-butanol


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