High??Yielding Synthesis of β??Octaalkyl??meso??(bromophenyl)??Substituted Porphyrins and X??ray Study of Axial Complexes of Their Zinc Complexes with THF and 1, 4 …

EA Mikhalitsyna, VS Tyurin, SE Nefedov…

Index: Mikhalitsyna, Elena A.; Tyurin, Vladimir S.; Nefedov, Sergey E.; Syrbu, Sergey A.; Semeikin, Aleksandr S.; Koifman, Oskar I.; Beletskaya, Irina P. European Journal of Inorganic Chemistry, 2012 , # 36 p. 5979 - 5990

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Citation Number: 7

Abstract

Abstract New 5-(4-bromophenyl)-3, 7, 12, 13, 17, 18-hexamethyl-2, 8-dipentyl-and 5, 15-bis (4-bromophenyl)-2, 8, 12, 18-tetramethyl-2, 8, 12, 18-tetrapentylporphyrins (H 2 P-1 and H 2 P-2) and their zinc metal complexes (ZnP-1 and ZnP-2, respectively) were synthesized in high yields by condensation of β-tetraalkyl-substituted dipyrromethanes with 2-formyl-3, 4- dialkylpyrroles or 4-bromobenzaldehyde and subsequent metallation. X-ray analysis data ...