Photosensitized oxygenation of twisted 1, 3-dienes: abnormally higher reactivity of vinyl hydrogen rather than allyl hydrogen toward singlet oxygen

H Mori, K Ikoma, S Isoe, K Kitaura…

Index: Mori, Hajime; Ikoma, Keiichi; Isoe, Sachihiko; Kitaura, Kazuo; Katsumura, Shigeo Journal of Organic Chemistry, 1998 , vol. 63, # 24 p. 8704 - 8718

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Citation Number: 24

Abstract

As one of the novel examples to investigate the characteristic reactivity of significantly twisted 1, 3-dienes, the photosensitized oxygenation of two types of significantly twisted 1, 3- dienes, cis-β-ionol derivative 2 and acyclic derivative 11, is investigated. Photosensitized ...