Bulletin of the Chemical Society of Japan

Structure and Reactivity of Small Ring Compounds. I. Solvolyses of Spiro [2, 4] hept-4-yl and Spiro [2, 5] oct-4-yl 3, 5-Dinitrobenzoates

T Tsuji, I Moritani, S Nishida

Index: Tsuji,T. et al. Bulletin of the Chemical Society of Japan, 1967 , vol. 40, # 10 p. 2338 - 2343

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Citation Number: 10

Abstract

The solvolyses of spiro [2, 4] hept-4-yl, spiro [2, 5] oct-4-yl, 2-methylenecyclopentyl, 2- methylenecyclohexyl, 2, 2-dimethylcyclopentyl, and 2, 2-dimethylcyclohexyl 3, 5- dinitrobenzoates have been examined in 60 wt% aqueous dioxane. The solvolysis rate of spiro [2, 4] hept-4-yl 3, 5-dinitrobenzoate was 850 times greater than that of the corresponding allyl derivative, the 2-methylenecyclopentyl ester, and 3.0× 10 5 times ...