Syntheses, Structures and Redox Properties of New Macrocyclic Triazatriolefinic Pd0 Complexes and Their Polypyrrole Modified Electrodes− Application to …

…, A Roglans, J Benet??Buchholz

Index: Llobet, Antoni; Masllorens, Ester; Rodriguez, Montserrat; Roglans, Anna; Benet-Buchholz, Jordi European Journal of Inorganic Chemistry, 2004 , # 8 p. 1601 - 1610

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Citation Number: 10

Abstract

Abstract New triolefinic macrocyclic ligands of the type (E, E, E)-1, 6, 11-tris (arenesulfonyl)- 1, 6, 11-triazacyclopentadeca-3, 8, 13-triene (aryl: a= ferrocenyl, b= 4-pyrrol-1-ylphenyl, c= 4- methylphenyl) and their Pd 0 complexes (1aab, 1abb and 1bcc) have been prepared and characterized. Further structural characterization in the solid state has also been performed by means of X-ray diffraction analysis for the complex 1bcc. The redox properties of both ...