On the Mechanism of the Dimethyldioxirane Oxidation of σH Adducts (Meisenheimer Complexes) Generated from Nitroarenes and Carbanions

W Adam, M Makosza, CG Zhao…

Index: Armillotta, Nicola; Bartoli, Giuseppe; Bosco, Marcella; Dalpozzo, Renato Synthesis, 1982 , # 10 p. 836 - 839

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Citation Number: 34

Abstract

... phenols from nitroarenes, a novel oxidation of preparative convenience for the synthesis of arenols ... It is known from Bartoli's work 6 that the Grignard reagents form relatively stable σ H ... 6 Similarly, the addition of an alkylmagnesium halide to 10-alkyl-9-nitroanthracene and ...