Synlett

Palladium-catalyzed direct C-3 arylations of indoles with an air-stable HASPO

L Ackermann, S Barfuesser

Index: Ackermann, Lutz; Barfuesser, Sebastian Synlett, 2009 , # 5 p. 808 - 812

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Citation Number: 27

Abstract

Abstract Efficient direct arylations of indoles occurred highly regioselectively at position C-3 with an in situ generated palladium complex derived from an air-stable HASPO, which enabled syntheses of diversely functionalized indoles, also with sterically hindered substrates.

~80%

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