Journal of Organometallic Chemistry

Cobaloximes with mixed dioximes having C and S side chains: Synthesis, structure and reactivity

G Dutta, BD Gupta

Index: Dutta, Gargi; Gupta Journal of Organometallic Chemistry, 2011 , vol. 696, # 14 p. 2693 - 2701

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Abstract

Abstract Ten mixed dioxime complexes RCo (L)(dmgH) Py [R= Cl, Me, Et, Bu, Benzyl][L= dSPhgH (1–5) and dSEtgH (6–10)] have been synthesized and characterized by NMR. Formation of 1 and 6 is very fast and takes only 5 and 15 min in ethanol. Molecular oxygen