(11BR,11′BR)-4,4′-(9,9-二甲基-9H-氧杂蒽-4,5-二基)双-二萘并[2,1-D:1′,2′-F][1,3,2]二噁磷杂庚英

更新时间:2024-01-02 09:41:22

(11BR,11′BR)-4,4′-(9,9-二甲基-9H-氧杂蒽-4,5-二基)双-二萘并[2,1-D:1′,2′-F][1,3,2]二噁磷杂庚英结构式
(11BR,11′BR)-4,4′-(9,9-二甲基-9H-氧杂蒽-4,5-二基)双-二萘并[2,1-D:1′,2′-F][1,3,2]二噁磷杂庚英结构式
品牌特惠专场
常用名 (11BR,11′BR)-4,4′-(9,9-二甲基-9H-氧杂蒽-4,5-二基)双-二萘并[2,1-D:1′,2′-F][1,3,2]二噁磷杂庚英 英文名 (11BR, 11'BR)-4,4'-(9,9-DIMETHYL-9H-XAN&
CAS号 349114-63-2 分子量 838.81900
密度 N/A 沸点 N/A
分子式 C55H36O5P2 熔点 198-217°C
MSDS 美版 闪点 N/A

 名称

中文名 (11BR,11′BR)-4,4′-(9,9-二甲基-9H-氧杂蒽-4,5-二基)双-二萘并[2,1-D:1′,2′-F][1,3,2]二噁磷杂庚英
英文名 (11bS,11'bS)-4,4'-(9,9-dimethyl-9H-xanthene-4,5-diyl)bis[dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin]
英文别名 更多

 物理化学性质

熔点 198-217°C
分子式 C55H36O5P2
分子量 838.81900
精确质量 838.20400
PSA 61.79000
LogP 17.91620
储存条件 室温

 安全信息

危险品运输编码 NONH for all modes of transport

 文献1

更多文献
An efficient catalyst system for the asymmetric transfer hydrogenation of ketones: remarkably broad substrate scope.

J. Am. Chem. Soc. 128 , 1044, (2006)

A BINOL-derived diphosphonite having a xanthene backbone is an excellent bidentate ligand in Ru-catalyzed 2-propanol-based transfer hydrogenation of aryl/alkyl and alkyl/alkyl ketones (ee = 76-99%). E...

 英文别名

(11bS,11'bS)-4,4'-(9,9-dimethyl-9H-xanthene-4,5-diyl)bis-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
(S,S)-4,5-bis(dinaphtho[d,f][1,3,2]dioxaphosphepin-4-yl)-9,9-dimethylxanthene
Xant-Bino
(S,S)-XantBino
(11bR,11'bR)-4,4'-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis-dinaphtho[2,1-d