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| 中文名 | 对苯二甲酸二丙烯酯 |
|---|---|
| 英文名 | bis(prop-2-enyl) benzene-1,4-dicarboxylate |
| 中文别名 | 对苯二甲酸二烯丙酯 |
| 英文别名 |
Diallylterephthalat
Diallyl terephthalate terephthalic acid diallyl ester Terephthalsaeure-diallylester 1,4-Benzenedicarboxylic acid,di-2-propenyl ester EINECS 213-835-2 diprop-2-en-1-yl benzene-1,4-dicarboxylate 1,4-Benzenedicarboxylic acid, di-2-propen-1-yl ester Diallyl terethiolate p-CH2CHCH2OOCC6H4COOCH2CHCH2 |
| 密度 | 1.1±0.1 g/cm3 |
|---|---|
| 沸点 | 349.9±22.0 °C at 760 mmHg |
| 分子式 | C14H14O4 |
| 分子量 | 246.259 |
| 闪点 | 171.3±20.7 °C |
| 精确质量 | 246.089203 |
| PSA | 52.60000 |
| LogP | 4.13 |
| 蒸汽压 | 0.0±0.8 mmHg at 25°C |
| 折射率 | 1.524 |
| 储存条件 | 2-8°C |
| 分子结构 | 1、 摩尔折射率：67.78 2、 摩尔体积（m3/mol）：221.4 3、 等张比容（90.2K）：554.1 4、 表面张力（dyne/cm）：39.2 5、 介电常数：无可用 6、 偶极距（10 -24cm 3）：无可用 7、 极化率：26.87 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:2.9 2.氢键供体数量:0 3.氢键受体数量:4 4.可旋转化学键数量:8 5.互变异构体数量:无 6.拓扑分子极性表面积52.6 7.重原子数量:18 8.表面电荷:0 9.复杂度:282 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：未确定。 2. 密度（g/cm3,25℃）：1.121 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,8mm）：176-178 7. 折射率（n 20/D ）：未确定 8. 闪点（ºC）：171 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
|
Diallyl Terephthalate
Revision number: 5
SAFETY DATA SHEET Section1. IDENTIFICATION Product name:Diallyl Terephthalate Revision number:5 Section2. HAZARDS IDENTIFICATION GHS classification PHYSICAL HAZARDSNot classified HEALTH HAZARDS Acute toxicity (Oral)Category 4 Category 2 Skin corrosion/irritation Serious eye damage/eye irritationCategory 2A Not classified ENVIRONMENTAL HAZARDS GHS label elements, including precautionary statements Pictograms or hazard symbols Signal wordWarning Hazard statementsHarmful if swallowed Causes skin irritation Causes serious eye irritation Precautionary statements: Do not eat, drink or smoke when using this product. [Prevention] Wash hands thoroughly after handling. Wear protective gloves/eye protection/face protection. [Response]IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Gently wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. [Disposal]Dispose of contents/container through a waste management company authorized by the local government. Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/mixture:Substance Components:Diallyl Terephthalate >98.0%(GC) Percent: CAS Number:1026-92-2 Diallyl Terephthalate Section3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms:Terephthalic Acid Diallyl Ester Chemical Formula:C14H14O4 Section4. FIRST AID MEASURES Remove victim to fresh air and keep at rest in a position comfortable for breathing. Inhalation: Get medical advice/attention if you feel unwell. Remove/Take off immediately all contaminated clothing. Gently wash with plenty of Skin contact: soap and water. If skin irritation or rash occurs: Get medical advice/attention. Rinse cautiously with water for several minutes. Remove contact lenses, if present Eye contact: and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion:Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Protection of first-aiders:A rescuer should wear personal protective equipment, such as rubber gloves and air- tight goggles. Section5. FIRE-FIGHTING MEASURES Suitable extinguishingDry chemical, foam, water spray, carbon dioxide. media: Unsuitable extinguishing Solid streams of water media: Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Remove movable containers if safe to do so. Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment. equipment for firefighters: Section6. ACCIDENTAL RELEASE MEASURES Use personal protective equipment. Keep people away from and upwind of spill/leak. Personal precautions, protective equipment and Ensure adequate ventilation. Entry to non-involved personnel should be controlled emergency procedures: around the leakage area by roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust). containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected up: material should be promptly disposed of, in accordance with appropriate laws and regulations. Section7. HANDLING AND STORAGE Precautions for safe handling Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment. Prevent generation of vapour or mist. Wash hands and face thoroughly after handling. Use a ventilation, local exhaust if vapour or aerosol will be generated. Advice on safe handling: Avoid contact with skin, eyes and clothing. Conditions for safe storage, including any incompatibilities Storage conditions:Keep container tightly closed. Store in a refrigerator. Store away from incompatible materials such as oxidizing agents. Heat-sensitive, Light-sensitive Packaging material:Comply with laws. Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls:Install a closed system or local exhaust as possible so that workers should not be exposed directly. Also install safety shower and eye bath. Personal protective equipment Respiratory protection: Vapor respirator. Follow local and national regulations. Diallyl Terephthalate Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Hand protection:Protective gloves. Eye protection:Safety glasses. A face-shield, if the situation requires. Skin and body protection: Protective clothing. Protective boots, if the situation requires. Section9. PHYSICAL AND CHEMICAL PROPERTIES Physical state (20°C):Liquid Clear Form: Colour:Colorless - Very pale yellow Odour:No data available pH: No data available Melting point/freezing point:No data available Boiling point/range:172°C/0.7kPa Flash point:158°C Flammability or explosive limits: Lower:No data available Upper:No data available Relative density:1.12 Solubility(ies): [Water]No data available [Other solvents]No data available Section10. STABILITY AND REACTIVITY Stable under proper conditions. Chemical stability: Possibility of hazardous No special reactivity has been reported. reactions: Incompatible materials: Oxidizing agents Hazardous decomposition Carbon monoxide, Carbon dioxide products: Section11. TOXICOLOGICAL INFORMATION Acute Toxicity:No data available Skin corrosion/irritation: No data available Serious eyeNo data available damage/irritation: Germ cell mutagenicity: No data available Carcinogenicity: IARC =No data available NTP =No data available Reproductive toxicity:No data available Section12. ECOLOGICAL INFORMATION Ecotoxicity: Fish:No data available No data available Crustacea: Algae:No data available Persistence / degradability: No data available BioaccumulativeNo data available potential(BCF): Mobility in soil Log Pow:No data available Soil adsorption (Koc):No data available No data available Henry's Law constant(PaM3/mol): Diallyl Terephthalate Section13. DISPOSAL CONSIDERATIONS Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when disposing of the substance. Section14. TRANSPORT INFORMATION Hazards Class:Does not correspond to the classification standard of the United Nations UN-No:Not listed Section15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002 and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were prescribed. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危险品运输编码 | UN 2810 |
|---|---|
| 包装等级 | III |
| 危险类别 | 6.1 |
| 海关编码 | 2917399090 |
|
~%
1026-92-2 |
| 文献：Journal of Polymer Science, , vol. 18, p. 335,337, 340 |
|
~%
1026-92-2 |
| 文献：US5387594 A1, ; |
|
~%
1026-92-2 |
| 文献：Synthesis, , # 1 p. 40 - 45 |
| 海关编码 | 2917399090 |
|---|---|
| 中文概述 | 2917399090 其他芳香多元羧酸. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途, 对苯二甲酸请注明4-CBA值, 对苯二甲酸请注明P-TL酸值, 对苯二甲酸请注明色度, 对苯二甲酸请注明水分 |
| Summary | 2917399090 aromatic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0% |
